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Hitt, Andrew; Wang, Fan; Li, Zeyuan; Ge, Mingyuan; Zhang, Youtian; Savsatli, Yavuz; Xiao, Xianghui; Lee, Wah-Keat; Stephens, Ryan; Tang, Ming (, Energy Storage Materials)
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Dai, Shuixing; Xiao, Yiqun; Xue, Peiyao; James Rech, Jeromy; Liu, Kuan; Li, Zeyuan; Lu, Xinhui; You, Wei; Zhan, Xiaowei (, Chemistry of Materials)
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Li, Zeyuan; Dai, Shuixing; Xin, Jingming; Zhang, Lin; Wu, Yang; Rech, Jeromy; Zhao, Fuwen; Li, Tengfei; Liu, Kuan; Liu, Qiao; et al (, Materials Chemistry Frontiers)We choose the high-performance nonfullerene acceptor ITIC-Th as an example, and incorporate electron-donating methoxy and electron-withdrawing F groups onto the terminal group 1,1-dicyanomethylene-3-indanone (IC) to construct a small library of four fused-ring electron acceptors. With this series, we systematically investigate the effects of the substituents on the end-groups on the electronic properties, charge transport, film morphology, and photovoltaic properties of the ITIC-Th series. The electron-withdrawing ability increases from methoxylated to unsubstituted, fluorinated, and difluorinated IC, leading to a downshift of energy levels and a redshift of absorption spectra. Optimized organic solar cells based on the ITIC-Th series show power conversion efficiencies ranging from 8.88% to 12.1%.more » « less
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